@Article{SilvaAlmOisCouFer:2019:ElDeCh,
author = "Silva, Lilian Mieko da and Almeida, Dalva Alves de Lima and Oishi,
Silvia Sizuka and Couto, Andrea Boldarini and Ferreira,
Neiden{\^e}i Gomes",
affiliation = "{Instituto Nacional de Pesquisas Espaciais (INPE)} and {Instituto
Nacional de Pesquisas Espaciais (INPE)} and {Instituto Nacional de
Pesquisas Espaciais (INPE)} and {Instituto Nacional de Pesquisas
Espaciais (INPE)} and {Instituto Nacional de Pesquisas Espaciais
(INPE)}",
title = "From electrode to device characterizations of polyaniline/micro
and nanodiamond/carbon fiber as ternary composites applied as
supercapacitor",
journal = "Journal of Solid State Electrochemistry",
year = "2019",
volume = "23",
number = "6",
pages = "1871--1885",
note = "Setores de Atividade: Administra{\c{c}}{\~a}o p{\'u}blica,
defesa e seguridade social.",
keywords = "capacitores eletroqu{\'{\i}}micos, diamante dopado, fibras de
carbono.",
abstract = "Production and characterization of polyaniline/boron-doped
diamond/carbon fiber (PAni/diamond/CF) ternary composites are
presented in this work, as well as the application as electrode
for a supercapacitor device. Different diamond morphologies were
evaluated, boron-doped nano- and microcrystalline diamond
(BDND/BDD). PAni was chemically synthetized in different
deposition times, from 10 to 60 min. FEG-SEM images showed
differences on PAni deposition for each condition. Raman and FTIR
analyses confirmed PAni formation as its conductive form. TGA
analyses exhibited the samples thermal behaviors. Through
electrochemical characterizations, PAni deposition time and
diamond influence were studied. Diamond films improved PAni
deposition and enhanced electrochemical reversibility, especially
BDD. For the 10-min deposition, diamond influence was better
observed, and the composites showed to be reversible even at high
scan rates. However, for 60 min, the electrodes presented a much
higher charge storage capacity. Therefore, BDD film with 60 min of
PAni deposition proved to be the best combination, in which the
composite presented a specific capacitance of 520 F g\−1 in
1 mol L\−1 H2SO4. Thus, this electrode was used for the
supercapacitor device assembly, exhibiting high capacitive
behavior, 99% of coulombic efficiency, 83% of capacitance
retention after 1000 cycles, and a tendency to stabilize
capacitance along the number of cycles.",
doi = "10.1007/s10008-019-04297-3",
url = "http://dx.doi.org/10.1007/s10008-019-04297-3",
issn = "1432-8488",
label = "lattes: 3273084621532688 5 SilvaLimOisCouFer:2019:ElDeCh",
language = "en",
targetfile = "Silva2019_Article_FromElectrodeToDeviceCharacter.pdf",
urlaccessdate = "27 abr. 2024"
}